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PDF Editor FAQ

Why is magnesium carbonate insoluble in water?

Well, solubility is an experimental property, and we should examine the data first …. but would you not expect [math]\text{a priori}[/math] that a SALT composed of a DICATION, and DIANION, to be LESS likely to undergo reaction with water than the salt composed of MONOCATION, and MONOANION, on the basis that such reaction involves disruption of a STRONGER ELECTROSTATIC BOND in the former case?And let us interrogate some data. Magnesium carbonate - Wikipedia suggests a solubility of [math]\text{150 ppm}[/math] at lab temperature, and interestingly, this solubility DECREASES with temperature…, which must be an entropy effect.

Does salt affect the solubility of organic solvents in water?

Yes. Dissolved salts make the water more polar, and make mixing with an organic solvent that much less favorable.In fact, a common lab technique — when you are having trouble separating your organic and aqueous layers and you need to break an emulsion — is to mix salt into the water layer. This is called “salting out.”

What is the solubility of salts in the volume of water?

Unknown until you do the experiment. Solubilities of salts in aqueous solution are extensively tabulated. Sometimes it is hard in the lab to reproduce these solubilities. But solubility is an EXPERIMENTAL proposition, an experiment you and I ain’t done….

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