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PDF Editor FAQ
Why are the melting point, boiling point and solubility of phenol in water higher than other molecules of similar molecular weight?
You shouldn't really think about boiling point in terms of molecular mass, it basically comes down to intermolecular forces.If the intermolecular forces that phenol experiences are stronger than others “of a similar molecular wright" if will have a higher boiling point.If the intermolecular forces that phenol experiences are weaker than others “of a similar molecular wright" if will have a lower boiling point.Always think in terms of forces when you are trying to rationalise boiling points.
Why is dissolution an exothermic process?
Dissolution is always exothermic in solubility of gases in liquids. But this is not always the case while dissolving solids in liquids. ( in dissolution of solids in liquids, it can be either endothermic or exothermic).Now to the question, why the dissolution is exothermic (in the solution of gases in liquids)?Answers lies in the fact, that when the gas particles are dissolved in the liquid, under given temperature and given pressure, the energy released and absorbed are as follows:-Energy is released in the form of heat of phase change when gas molecules dissolve in the liquid as they undergo condensation while entering the liquid to change themselves into a liquid phase.Energy is not required to break the intermolecular forces of gaseous molecules for very obvious reason (as they are gases and have very very very weak intermolecular forces)Energy is required to break the intermolecular bonds of water.Energy is released when the intermolecular bonds are formed between gaseous molecules and water molecules.Thus while summing up, the energy released is much more than the energy required, therefore it is an EXOTHERMIC PROCESS.
Does the boiling point and melting point affect the solubility of a compound?
The boiling point and melting point do not affect the solubility of a compound (unless you intentionally go trying to dissolve them at these temperatures which resist solvation). What affects the solubility, melting point, and boiling point however, are intermolecular forces, the attractive forces between each molecule in a compound.Higher intermolecular forces result in higher boiling points and melting points. Solubility however, is a bit more complicated.This only affects the solubility if the intermolecular forces of the solute and solvent are compatible (polar forces and non polar forces), and if the attractive forces of the solute to itself and the solvent to itself are stronger then the forces between each other.
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