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PDF Editor FAQ

How do I determine if a molecule is linear or bend?

Molecular shapes can be predicted using Lewis diagrams and the VSEPR theory.Molecules that consist of three atoms (ie; AX2) may be linear or bent.When you draw the Lewis structure of the molecule, the arrangement of electron pairs around the central atom will determine the shape because electron pairs will arrange themselves symmetrically around the central atom. If all electrons pairs are acting as bonding electrons, leaving no lone pair on the central atom (AX2), then the molecule will be linear (eg; CO2). If, however, there is one or two lone pairs (E) on the central atom, then the molecule will be bent (AX2E eg; SO2, AX2E2 eg; H2O).

What are the three possible Lewis structures of ClF3?

No - there is only one Lewis structure.Do you mean the shape, as this is based on the trigonal bipyramid. You need to use VSEPR theory to determine the shape with the least amount of electron pair repulsion.

What is the molecular shape of IO2F?

O.K., this is actually a fairly straight-forward application of VSEPR, but it is going to be built on a Lewis structure, so let's draw the Lewis structures first.To draw the Lewis Structure:Start with a blank piece of paper. Put the least electronegative element in the center (I). O.K., now put the three other atoms ( 2xO and 1xF) around it, probably as a triangle.Count up the electrons: I:7, F:7, 2xO: 12; total = 26.Put one pair of electrons between each atom and the center atom (I). that's 3 pairs total or 6 electrons. Leaves us with 20.Now, starting with the most electronegative atom (F), fill the octet by adding three more pairs of electrons. (leaves 14) Do the same for the next most electronegative element (2xO will take 2x3 more pairs for a total of 12 electrons used). That leaves 2 electrons for Iodine. Put the unshared electron pair on Iodine.O.K., so now we can do the VSEPR structure:1) Count up the number of electron groups. A group is defined as a single, double, or triple bond or an unshared electron pair. In this case we have three bonds and an unshared electron pair.2) Determine the Electronic structure: Easy enough: 4 electron groups is tetrahedral.3) Determine the Molecular geometry by taking into account only the arrangement of the atoms: IN this case, by ignoring the unshared electron pair we see the remaining structure is a trigonal pyramid.VSEPR theory isn't all that difficult. Generally a beginning chemistry student requires 2-4 hours of practice (homework!) to become expert in predicting molecular geometries.Good luck!

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