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PDF Editor FAQ

What factors determine the molar volume of liquids?

Molecular size is a major factor.Molecules that are large will take a larger volume to fit them in.Liquids are relatively close packed compared to gases.For gases, at a reasonable pressure, not a huge pressure, most of the space occupied is empty and there are large distances between the molecules. So molecular aize does not impact much on molar volume.For liquids, the proximity of molecules to each other means that size is a major factor.There is also some influence of molecular shape and polarity of the molecules.Some molecules have shapes that allow for closer packing than others. Polar molecules can have their packing arrangements affected by dipole-dipole interactions.

Is CO2 linear or not?

Co2 is a linear triatomic molecule. Each C = O bond is polar because O more electronegative than C, so O is the partial negative end of the bond dipole.The double bond behaves just like a single bond for purposes of predicting molecular shape.This compound has two groups of electrons around the carbon. According to VSEPR theory, the two sets of electrons will orient themselves 180o apart, on opposite sides of the carbon atom, minimizing electron repulsion. Therefore the molecular structure of CO2 is linear.Double and triple bonds involve more electron pairs than single bonds, but this has little effect on the overall molecular shape. All of the electron pairs in a multiple bond are shared between the same two nuclei and therefore occupy the same region of space.All electron pairs in a multiple bond count as one bond and contribute to molecular geometry the same as a single bond does. The carbon atom in C02has no lone pairs and participates in two double bonds. Each double bond counts as one for the purpose of predicting geometry so the structure of CO2 is linear.

What are the similarities and differences of CH4 and CH3OH in terms of molecular shapes and polarity?

Similarities:CH4 and CH3OH are covalent compounds since they are formed by covalent bonds.The geometrical structure of both compounds is tetrahedral.CH4 is the first member of alkane but methanol is the first member of alcohol.Both takes part in combustion reaction.Dissimilarities: Although methane is non-polar but due to the electronegativity difference between O and H in hydroxyl group of methanol is a polar compound. CH4 is not soluble in water but CH3OH is not. The molecules of CH4 are attracted by weak Vander Waals force or London dispersion force. The CH3OH molecules formed hydrogen bond, so dipole-dipole interaction takes place.

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