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PDF Editor FAQ

Why is lowering of vapour pressure not a colligatIve property?

I think you got the wrong concept of colligative properties. Colligative properties of solution are those which do not depend upon the nature of solute but on the quantity of solute in a solution. So this takes lowering of vapour pressure out of the question because vapour pressure and it's decrease would depend upon the nature of solute. But relative Lowering of vapour pressure is a colligative property as it sees the lowering of vapour pressure of a solution wrt solvent is a colligative property as it depends upon th quantity of solute rather than its nature.Hope this helps.For any further quarries feel free to message me.

Why is the molecular mass of polymers determined by osmotic pressure and not by other colligative properties?

Here I am quoting the NCERT textbook which you ought to have read if you are writing class 12 boards especially CBSE."The Osmotic pressure method has the advantage over other methods as pressure measurement is around room temperature and the molarity of the solution is used instead of molality.As compared to other colligative properties, its magnitude is large even for very dilute solutions. The technique of osmotic pressure for determination of molar mass of solutes is particularly useful for biomolecules as they are generally not stable at high temperatures and polymers have poor solubility."So for your next board exam read the textbook.Source:Chemistry part 1 (page number 54)NCERT textbook

'' the non volatile nature will included in the nature of solute" if this statement is correct then why colligative does not depends on nature of solute Plzz explain?

Man!!!!!Colligative properties depends upon no of solute particles present, not on type of solute particles 🥺.“Non volatile Nature will be included in nature of solute” corresponds to this fact only that “ if solute particles are volatile, its number will change with passage of time, so as colligative properties will”.Understand this funda:Solute particles must possess: Non volatile Nature because no of solute particles remain fix, then constant property is observed (freezing point, melting point etc). Study become easier.Point to notice: Since colligative itself says, it depends on “number" , so to observe behaviour of any solution you need to have fix basic properties.ORIn most simple way:If solute particles are Volatile, then basic definition of colligative properties aren't satisfied. Colligative properties are studied for Non Volatile solute particles 😁.Add on:If you think why we take “solute “ as only determining factor, reason is simple. Its solute particles that decide properties of solutions.Eg- Add a pinch of salt in water, its vapour pressure changes(decrease in this case). This is due to fact that: external solute particles are added. This is reason why, solute particles are base for Colligative properties.

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