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What kind of metal are the meteorites found in Chaco, Argentina made of? Are they any special?
You might refer to the meteorite found in Campo del Cielo (Field of Heaven), Chaco Province, Argentina, in 2016.World's second-largest meteorite 'Gancedo' discovered in ArgentinaIt was named Gancedo meteorite with a mass of around 30 metric tons.The area is rich in meteorites, spread with what is believed to be the breaking into pieces of a larger incident object (with a pre-atmospheric mass of at least 840 tons [1][1][1][1] )The estimated time of fall is between 4,000 to 6,000 years ago.Campo del Cielo MeteoriteCampo del Cielo Meteorite (Field of Heaven)As per the question,The average composition of the Campo del Cielo meteorites is 6.67% Ni, 0.43% Co, 0.25% P, 87 ppm Ga, 407 ppm Ge, and 3.6 ppm Ir, with the rest being iron.Professor William A. Cassidy (an American geologist and professor emeritus of Geology and Planetary Science at the University of Pittsburgh) studied Campo del Cielo for years.William A. Cassidy - Wikipediaa) Earliest Publication:“Meteorites and Craters of Campo del Cielo, Argentina”William A. Cassidy, Luisa M. Villar, Theodore E. Bunch, Truman P. Kohman and Daniel J. MiltonScienceNew Series, Vol. 149, No. 3688 (Sep. 3, 1965), pp. 1055-1064Available through JSTOR[2][2][2][2]b) Other PublicationsFrom LPI (Lunar and Planetary Institute)https://www.lpi.usra.edu/lunasearch/?cx=002803415602668413512%3Al1gr0lrmbrc&cof=FORID%3A11&q=Campo+del+cielo&sa=Search&siteurl=https%3A%2F%2Fwww.lpi.usra.edu%2Flunar%2Fc) Report on the pre-atmospheric mass studyMeteoritics & Planetary Science Volume 37, Issue 2. Available through Wiley Library at [3][3][3][3]ReferenceLIBERMAN, R. G., NIELLO, J. O., TADA, M. L., FIFIELD, L. K., MASARIK, J. and REEDY, R. C. (2002), Campo del Cielo iron meteorite: Sample shielding and meteoroid's preatmospheric size. Meteoritics & Planetary Science, 37: 295-300. doi:10.1111/j.1945-5100.2002.tb01111.xI hope this helps!Footnotes[1] Meteoritics & Planetary Science[1] Meteoritics & Planetary Science[1] Meteoritics & Planetary Science[1] Meteoritics & Planetary Science[2] Meteorites and Craters of Campo del Cielo, Argentina[2] Meteorites and Craters of Campo del Cielo, Argentina[2] Meteorites and Craters of Campo del Cielo, Argentina[2] Meteorites and Craters of Campo del Cielo, Argentina[3] Meteoritics & Planetary Science[3] Meteoritics & Planetary Science[3] Meteoritics & Planetary Science[3] Meteoritics & Planetary Science
In details. How does molecular vibration works in a diatomic were there is double or triple bonds for example O2 or N2?
Generally, as you increase the bond strength of a bond in a molecule, you will do two things to the oscillator energy curve of that bond. As the bond grows stronger, the depth of the oscillator energy curve increases and also increases the spacing between the individual energy levels. This makes the bond harder to break apart, and requires more energy than before. Another effect of bond strengthening is bond shortening, and this shifts the oscillator energy curve towards short bond distances. The shortening of the bond also increases the slope of the nuclear repulsion region, in effect narrowing the oscillator energy curve around the zero point energy (v=0) region. This set of diagrams (drawn by me) shows what different anharmonic oscillator energy curves look like for carbon-carbon bonds.With shortened bonds, the carbon-carbon stretching frequency INCREASES. This is easily observed by comparing infrared spectra of acetylene, ethylene, and ethane, which have been computed (they are all IR-silent in experimental environments, as they lack dipole moments). By looking at the stretching vibrations of the carbon-carbon atoms we find the following wavenumber values for the three different bond types:A single C-C bond vibrates at 1055/cmA double C-C bond vibrates at 1694/cmA triple C-C bond vibrates at 2114/cmWe immediately see that the stronger C-C bonds are vibrating at higher frequencies, compared to the weaker C-C bonds. The strong C-C bonds also have higher bond dissocation energies compared to the weak C-C bonds. A quick look at the bond dissocation energies of the three C-C bond types gives us more information on the depth of their oscillator energy curves.A single C-C bond needs 83-85 kilojoules per mole to break apart.A double C-C bond needs 146-151 kilojoules per mole to break.A triple C-C bond needs 200 kilojoules per mole to break.The amounts of energy provided here is the amount of energy you need to break all the C-C bonds in 6.022x10^23 molecules containing the same bond! High dissociation energies arise from very deep oscillator wells, as you need to excite the molecule a lot more compared to a bond with low dissociation energy (which has a shallow oscillator well).A table of different second-row element bonds can be used to compare double and triple bonds against single bonds. Higher wavenumber (the unit used in infrared spectroscopy) represent a higher vibrational frequency. Bonds that show high wavenumber (in units of inverse centimeters) have deep oscillator wells and require a lot of energy to dissociate the bonds completely. A high wavenumber also means a stronger bond, a shorter bond, and a bond requiring more energy to break, compared to a bond exhibiting low wavenumber. A bond that vibrates at 2000/cm is stronger than one that vibrates at 1000/cm.The table for different second-row bonds is below:It becomes easy to see that multiple bonds have higher wavenumber compared to single bonds, and hence need more energy to break apart. Multiple bonds vibrate at higher frequencies and are consequently harder to excite, as the spacing in a narrow oscillator well is larger than that in a shallow oscillator well. Increasing the bond strength of a bond with extra orbital interactions is likely to make the oscillator well deeper, narrower, and shifted towards short bond distances.
I'm an SC category candidate. What is the minimum rank needed for me to be selected in IAS through the civil service exam?
You can generally get it. Upto 500 or 560.But it is not every time fixed. It fluctuates at every time. It will be better that you focus on the best. If you do your best definitely you can get through IAS.Some of.the information is as follows. It is very useful as it shows the cut off marks and cut of rank of IAS of the respective category which you want.Upto Which Rank Can An Aspirant Get Into IAS, IPS or IFS?More than 11.3 lakh aspirants applied for UPSC Civil Services Exam in 2016. But what is the last rank that can fetch an aspirant the prestigious IAS (Indian Administrative Service)? The answer lies in the number of vacancies reported for a year and the category an aspirant belongs.But a comparative analysis will help aspirants get a good idea about the cut-off ranks for IAS, IPS or IFS. In this post, we present the final ranks for six services (IAS, IPS, IFS, IRS-IT, IRS-C&CE and IAAS) from each of the categories – general, OBC, SC, and ST – for last 9 years (from 2007-2015).2015: Final Rank Allocated for IAS, IPS, IFS etc.The figure marked in ‘black’ is the final rank while the figure in ‘red’ is the total marks of the candidate. In 2015, 96 was the last all-India rank, which fetched a candidate belonging to the general category IAS. The candidate had secured 930 out of 2025 marks. At the same time, the last OBC candidate who secured entry into IAS had an all-India rank of 446 with a total 886 marks out of 2025. The last rank which fetched IAS was 595 and 620 for SC and ST respectively.2014: Final Rank Allocated for IAS, IPS, IFS etc.The figure marked in ‘black’ is the final rank while the figure in ‘red’ is the total marks of the candidate. In 2014, 95 was the last all-India rank, which fetched a candidate belonging to the general category IAS. The candidate had secured 953 out of 2025 marks. At the same time, the last OBC candidate who secured entry into IAS had an all-India rank of 466 with a total of 905 marks out of 2025. The last rank which fetched IAS was 650 and 773 for SC and ST respectively.2013: Final Rank Allocated for IAS, IPS, IFS etc.In 2013, 91 was the last all-India rank, which fetched a candidate belonging to the general category IAS. At the same time, the last OBC candidate who secured entry into IAS had an all-India rank of 384. It was 534 and 802 for SC and ST respectively.2012: Final Rank Allocated for IAS, IPS, IFS etc.In 2012, 116 was the last all-India rank, which fetched a candidate belonging to the general category IAS. At the same time, the last OBC candidate who secured entry into IAS had an all-India rank of 266. It was 619 and 720 for SC and ST respectively.Understanding the DoPT allocation detailsIt should be noted that the details mentioned above are based on the allocation of candidates to different services based on the first rank list. We have not included the consolidated reserve list (supplementary list)here.To understand the same better, consider the 2015 case.Though the total vacancies were 1164, UPSC in its first recommended list allocation only 1078 aspirants and put 86 candidates on the reserve list.Out of 1078, due to various reasons, DoPT, considered for allocation only 1055 candidates, which we have mentioned in each of the tables as ‘Total number of candidates’. This should be understood as the total number of candidates considered for allocation.Again, it should be noted that in 2015, out of the total 1055 candidates considered for allocation, DoPT allocated only 969 candidates, due to various reasons like medical, lack of certificates etc.In short, getting into any of the 24 services is not easy! But we feel a proper understanding of these details will help aspirants to understand ground realities and prepare harder with a clear mind and sharp goals.Hope, it will help.
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