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How is it possible for matter and anti-matter to annihilate each other, if the first law of thermodynamics states that matter can't be created nor destroyed?

That’s easy. The first law of thermodynamics doesn’t say matter can’t be created or destroyed.No law of physics says matter can’t be created or destroyed. Matter is created and destroyed all the time.Schoolchildren are sometimes taught the “law” that matter can’t be created or destroyed by chemical reactions in elementary school. Even this is not technically correct; it’s a lie-to-children.Lie-to-children - WikipediaMass depends on energy content; that’s what [math]E=mc^2[/math] means. Even in chemical reactions, mass can change by a very, very tiny amount. Chemical reactions can’t change the number of particles, but nuclear reactions can, and do, all the time. “Matter” is not a conserved quantity.When a particle and its antiparticle annihilate, they produce energy, according to…you guessed it…[math]E=mc^2[/math].

Has there ever been a time in our universe that there was more or less matter than right now?

A2A. Short answer: Yes. Long answer: You have to remember that matter and energy are two forms of the same thing.A lot of people hear “matter can neither be created nor destroyed.” This is generally true(ish) for chemical reactions, so it is often taught in grade school science classes. It is not true of nuclear reactions.For example, matter-antimatter annihilation results in the conversion of matter to energy (specifically, gamma photons). After a matter-antimatter reaction, there is less matter than there used to be.Other kinds of nuclear reactions also result in a net loss or gain of matter.What can’t be created or destroyed is mass-energy. Matter can turn into photons and photons can turn into matter, so the amount of matter can change, but mass-energy is conserved.

What is an example of the law of conservation of mass?

There is no mass conservation in relativistic description of nature in which mass is just one of the form of energy and what is really conserved is mass-energy. In case of non-relativistic approach one can assume mass is conserved as it was descovered in the past in the domain of chemical reactions. Conservation of Mass-Energy – Mass-Energy Equivalence

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