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PDF Editor FAQ
Why is OH2 “hydroxide” in words and not “oxygen dihydrogen” (as “O” represents oxygen and “H” represents hydrogen, and as they are 2 elements, we add “di” (which means “two” in Greek prefix) to the word hydrogen)?
That’s not how we name compounds.LibreTexts, as usual, has some good information - in this case, about how to name a binary covalently-bonded compound. Per their directions:Place the elements in their proper order.The element farthest to the left in the periodic table is usually named first. If both elements are in the same group, the element closer to the bottom of the column is named first.The second element is named as if it were a monatomic anion in an ionic compound (even though it is not), with the suffix -ide attached to the root of the element name.Identify the number of each type of atom present.Prefixes derived from Greek stems are used to indicate the number of each type of atom in the formula unit (Table 2.8.2[math]2.8.2[/math]). The prefix mono- (“one”) is used only when absolutely necessary to avoid confusion, just as the subscript 1 is omitted when writing molecular formulas.Since hydrogen is further to the left on the periodic table, it will come first. As you rightly point out, there are two of them, so it should take the Greek prefix di-. This should be placed before the oxygen, which we’re supposed to pretend is an anion (even if it isn’t) and add the suffix -ide. There’s only one oxygen, so we could add the prefix mono- if we wanted to, but strictly speaking we don’t need to. Then, we simply put these parts together with the further-left element coming first (as if it were a cation) and the further-right element coming second (as if it were an anion).Hence, dihydrogen oxide. (or dihydrogen monoxide)Or, maybe you prefer to analyze this compound as an ionic compound. This isn’t actually true, though its bonds are very polar, but its composition is such that, coincidentally, there are two combinations of ions that give the same formula.First, you can analyze it as an H[math]^+[/math] (hydrogen) cation plus an OH[math]^-[/math] (hydroxide) anion. Under this system, such an ionic compound would be called hydrogen hydroxide.Or you can analyze it as 2 H[math]^+[/math] (hydrogen) cations plus a single O[math]^{-2}[/math] (oxide) anion. Ionic compound naming rules don’t require that you give the same Greek prefixes to indicate the number of each ion, since the charge of the anion (-2) relative to the charge of the cation (+1) implies the number of cations needed (2) to make the substance charge-neutral, and vice versa. Hence, hydrogen oxide.We can take this a step further.This compound meets the definition of a Brønsted-Lowry acid (albeit a very weak one) as the oxygen can steal the electrons from one of the O-H bonds leaving an H[math]^+[/math] ion that can be picked up by some other molecule. Such acids are named according to their anionic conjugate base (what’s left over after removing the H[math]^+[/math] ion) plus the word “acid” (which implies the presence of an H[math]^+[/math] ion). Since the conjugate base here is OH[math]^-[/math] (hydroxide), we could call this compound hydroxic acid.So which of these names is right?Well, none of them.OH[math]_2[/math] is in a kind of strange order. It’s better known by the formula H[math]_2[/math]O (again, the element furthest on the left of the periodic table comes first), which has a much better-known name:Water.
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