Chapter 13: Nuclear Magnetic Resonance (Nmr) Spectroscopy: Fill & Download for Free

The Joint Admission Test (JAM) to Master of Science (http://M.Sc.) is conducted by the Indian Institutes of Technology ( IITs) for admission to Integrated Ph.D degree programs at the Indian Institute of Science, Bangalore (IISc) and http://M.Sc (2 year), Joint http://M.Sc-Ph.D, M.Sc-Ph.D Dual Degree, M.Sc-M.Tech and other Post-Bachelor's degree programs at the 13 IITs.In a given academic year, any one of the IITs take the responsibility for conducting the JAM test. IITs offer post graduate education in different disciplines of basic and applied sciences. These institutes have been administering JAM since 2004 for admission to http://M.Sc. and other Post http://B.Sc. courses. The main objective of the JAM test is to encourage science as a career option.IIT JAM Chemistry SyllabusChemistry is the branch of science concerned with the substances of which matter is composed, the investigation of their properties and reactions, and the use of such reactions to form new substances. For this session, the important topics for chemistry paper are as follows:hysical ChemistryUnit - 1: Basic Mathematical ConceptsFunctions; maxima and minima; integrals; ordinary differential equations; vectors and matrices; determinants; elementary statistics and probability theory.Unit - 2: Atomic and Molecular StructureFundamental particles; Bohr’s theory of hydrogen-like atom; wave-particle duality; uncertainty principle; Schrödinger’s wave equation; quantum numbers; shapes of orbitals; Hund’s rule and Pauli’s exclusion principle; electronic configuration of simple homonuclear diatomic molecules.Unit - 3: Theory of GasesEquation of state for ideal and non-ideal (van der Waals) gases; Kinetic theory of gases; Maxwell-Boltzmann distribution law; equipartition of energy.Unit - 4: Solid StateCrystals and crystal systems; X-rays; NaCl and KCl structures; close packing; atomic and ionic radii; radius ratio rules; lattice energy; Born-Haber cycle; isomorphism; heat capacity of solids.Unit - 5: Chemical ThermodynamicsReversible and irreversible processes; first law and its application to ideal and nonideal gases; thermochemistry; second law; entropy and free energy; criteria for spontaneity.Unit - 6: Chemical and Phase EquilibriaLaw of mass action; Kp, Kc, Kx and Kn; effect of temperature on K; ionic equilibria in solutions; pH and buffer solutions; hydrolysis; solubility product; phase equilibria–phase rule and its application to one-component and two-component systems; colligative properties.Unit - 7: ElectrochemistryConductance and its applications; Transport number; Galvanic cells; EMF and free energy; concentration cells with and without transport; polarography; concentration cells with and without transport; Debey-Huckel-Onsagar theory of strong electrolytes.Unit - 8: Chemical KineticsReactions of various order; Arrhenius equation; collision theory; transition state theory; chain reactions – normal and branched; enzyme kinetics; photochemical processes; catalysis.Unit - 9: AdsorptionGibbs adsorption equation; adsorption isotherm; types of adsorption; surface area of adsorbents; surface films on liquids.Unit - 10: SpectroscopyBeer-Lambert law; fundamental concepts of rotational, vibrational, electronic and magnetic resonance spectroscopy.IIT JAM Syllabus for Organic ChemistryUnit - 1: Basic Concepts in Organic Chemistry and StereochemistryElectronic effects (resonance, inductive, hyperconjugation) and steric effects and its applications (acid/base property); optical isomerism in compounds with and without any stereocenters (allenes, biphenyls); conformation of acyclic systems (substituted ethane/n-propane/n-butane) and cyclic systems (mono- and di-substituted cyclohexanes).Unit - 2: Organic Reaction Mechanism and Synthetic ApplicationsChemistry of reactive intermediates (carbocations, carbanions, free radicals, carbenes, nitrenes, benzynes etc.); Hofmann-Curtius-Lossen rearrangement, Wolff rearrangement, Simmons-Smith reaction, Reimer-Tiemann reaction, Michael reaction, Darzens reaction, Wittig reaction and McMurry reaction; Pinacol-pinacolone, Favorskii, benzilic acid rearrangement, dienone-phenol rearrangement, Baeyer-Villeger reaction; oxidation and reduction reactions in organic chemistry; organometallic reagents in organic synthesis (Grignard, organolithium and organocopper); Diels-Alder, electrocyclic and sigmatropic reactions; functional group inter-conversions and structural problems using chemical reactions.Unit - 3: Qualitative Organic AnalysisIdentification of functional groups by chemical tests; elementary UV, IR and 1H NMR spectroscopic techniques as tools for structural elucidation.Unit - 4: Natural Products ChemistryChemistry of alkaloids, steroids, terpenes, carbohydrates, amino acids, peptides and nucleic acids.Unit - 5: Aromatic and Heterocyclic ChemistryMonocyclic, bicyclic and tricyclic aromatic hydrocarbons, and monocyclic compounds with one hetero atom: synthesis, reactivity and properties.IIT JAM Syllabus for InOrganic ChemistryUnit - 1: Periodic TablePeriodic classification of elements and periodicity in properties; general methods of isolation and purification of elements.Unit - 2: Chemical Bonding and Shapes of CompoundsTypes of bonding; VSEPR theory and shapes of molecules; hybridization; dipole moment; ionic solids; structure of NaCl, CsCl, diamond and graphite; lattice energy.Unit - 3: Main Group Elements (s and p blocks)General concepts on group relationships and gradation in properties; structure of electron deficient compounds involving main group elements.Unit - 4: Transition Metals (d block)Characteristics of 3d elements; oxide, hydroxide and salts of first row metals; coordination complexes: structure, isomerism, reaction mechanism and electronic spectra; VB, MO and Crystal Field theoretical approaches for structure, color and magnetic properties of metal complexes; organometallic compounds having ligands with back bonding capabilities such as metal carbonyls, carbenes, nitrosyls and metallocenes; homogenous catalysis.Unit - 5: Bioinorganic ChemistryEssentials and trace elements of life; basic reactions in the biological systems and the role of metal ions, especially Fe2+, Fe3+, Cu2+ and Zn2+; structure and function of hemoglobin and myoglobin and carbonic anhydrase.Unit - 6: Instrumental Methods of AnalysisBasic principles; instrumentations and simple applications of conductometry, potentiometry and UV-vis spectrophotometry; analysis of water, air and soil samples.Unit - 7: Analytical ChemistryPrinciples of qualitative and quantitative analysis; acid-base, oxidation-reduction and complexometric titrations using EDTA; precipitation reactions; use of indicators; use of organic reagents in inorganic analysis; radioactivity; nuclear reactions; applications of isotopes.Let Us Look at a videoPreparation TacticsSince IIT-JAM chemistry examination is designed considering graduate-level chemistry subject knowledge, you should be focused on clearing conceptual knowledge.You should start preparation with complete determination and fix your timetable accordingly.Stick to the syllabus – Before starting preparation, analyze the syllabus and try to cover the complete syllabus. If you check the table given below, you will see that all topics have equal weightage in IIT-JAM. So don’t skip any topic because each topic is equally important. If you skip any topic, it may affect your rank.For more help you can contact Sourav Sir’s Classes at +919836793076/+918697585572/+919903950424. VISIT WEBSITE https://www.souravsirclasses.com/